Pt-free cathode catalysts prepared via multi-step pyrolysis of Fe phthalocyanine and phenolic resin for fuel cells.

Retraction for Chemical Communications: Pt-free cathode catalysts prepared via multi-step pyrolysis of Fe phthalocyanine and phenolic resin for fuel cells

Enhanced Electrocatalytic Activity of Pt-M (M= Co, Fe) Chitosan Supported Catalysts for Ethanol Electrooxidation in Fuel Cells

Here, metal nanoparticles were synthesized by chemical reduction of the corresponding metal salts in the presence of chitosan polymer. Binary and ternary metallic-chitosan Pt-Fe-CH, Pt-Co-CH and Pt-Fe-Co-CH nanocomposites were prepared. Transmission electron microscopy images and UV–Vis spectra of the nanocomposites confirmed the presence of the metal nanoparticles. The electrocatalytic activit...

Design of Iron(II) Phthalocyanine‐Derived Oxygen Reduction Electrocatalysts for High‐Power‐Density Microbial Fuel Cells

Iron(II) phthalocyanine (FePc) deposited onto two different carbonaceous supports was synthesized through an unconventional pyrolysis-free method. The obtained materials were studied in the oxygen reduction reaction (ORR) in neutral media through incorporation in an air-breathing cathode structure and tested in an operating microbial fuel cell (MFC) configuration. Rotating ring disk electrode (...

Active site formation mechanism of carbon-based oxygen reduction catalysts derived from a hyperbranched iron phthalocyanine polymer

Carbon-based cathode catalysts derived from a hyperbranched iron phthalocyanine polymer (HB-FePc) were characterized, and their active-site formation mechanism was studied by synchrotron-based spectroscopy. The properties of the HB-FePc catalyst are compared with those of a catalyst with high oxygen reduction reaction (ORR) activity synthesized from a mixture of iron phthalocyanine and phenolic...

Effect of Pt on Zn-Free Cu-Al Catalysts for Methanol Steam Reforming to Produce Hydrogen

Steam reforming of methanol can be considered as an attractive reaction aiming at hydrogen production for PEM fuel cells. Although Cu/Al-contained catalysts are considerably evaluated in this reaction, further evaluation is essential to evaluate the impact of some promoters like Pt in order to find a comprehensively optimized catalyst. Pt promoter is employed with different methods in this ...